Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea

نویسندگان

  • Joel T. Mague
  • Shaaban K. Mohamed
  • Mehmet Akkurt
  • Omran A. Omran
  • Mustafa R. Albayati
چکیده

In the title compound, C13H13N3O, the phenyl ring makes a dihedral angle of 47.0 (1)° with the mean plane of the -NC(=O)N- unit, while the dihedral angle between the latter mean plane and the amino-phenyl ring is 84.43 (7)°. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds involving the central -NHC(=O)NH- units, forming chains running parallel to the b axis. These chains associate with one another via N-H⋯O and N-H⋯N hydrogen bonds, from the pendant amino groups to the -NHC(=O)NH- units of adjacent mol-ecules, forming columns propagating along [010]. The structure was refined as a two-component twin with a 0.933 (3):0.067 (3) domain ratio.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

2-(1-Adamant­yl)-1-(3-amino­phen­yl)ethanol

In the crystal structure of the title compound, C(18)H(25)NO, mol-ecules are linked via O-H⋯N hydrogen bonds, forming chains parallel to the c axis. Additional weak N-H⋯O inter-actions stabilize the crystal packing. The adamantane cage consists of three fused cyclo-hexane rings in almost ideal chair conformations, with C-C-C angles in the range 107.9 (10)-111.3 (11)°.

متن کامل

1-[3-(Hy­droxy­meth­yl)phen­yl]-3-phenyl­urea

In the title compound, C(14)H(14)N(2)O(2), the dihedral angle between the benzene rings is 23.6 (1)°. The H atoms of the urea NH groups are positioned syn to each other. In the crystal, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

متن کامل

1,1′-(Propane-1,3-di­yl)bis­(3-phenyl­urea)

The title compound, C(17)H(20)N(4)O(2), has crystallographic inversion symmetry. In the crystal structure, inter-molecular hydrogen bonding between adjacent urea groups gives rise to infinite polymeric chains diagonally across the bc plane. With a centroid-centroid distance of 3.295 (2) Å, π-π stacking is present in the crystal along the same plane.

متن کامل

1-(4-Amino­phen­yl)-3-[2-(trifluoro­meth­yl)phen­yl]prop-2-en-1-one

The title compound, C(16)H(12)F(3)NO, a derivative of biologically active chalcones, comprises two benzene rings and a central -CH=CH-C(=O)- unit. The dihedral angle between the two rings is 10.9 (1)° and the mol-ecule adopts an E configuration about the central olefinic bond. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds.

متن کامل

(2E)-1-(4-Amino­phen­yl)-3-(2,4-dichloro­phen­yl)prop-2-en-1-one

The title compound, C(15)H(11)Cl(2)NO, is approximately planar (r.m.s. deviation = 0.062 Å) and contains a single C=C double bond in a trans (E) configuration. The crystal packing is stabilized by intermolecular N-H⋯N and N-H⋯O inter-molecular hydrogen bonding.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 71  شماره 

صفحات  -

تاریخ انتشار 2015